Classifications

• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
  • C08K5/00—Use of organic ingredients
  • C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
  • C08K5/0033—Additives activating the degradation of the macromolecular compound

Definitions

• the invention relates to a plastic composition, the polymeric component of which comprises a thermoplastic polymer, in particular a polymer of ⁇ -olefins, preferably polyethylene or ethylene copolymers, which are too small either under the action of heat and from ultraviolet light and / or from sunlight and / or under composting conditions Sharing disintegrates. Since this plastic composition also contains a natural, biodegradable substance, the resulting small plastic parts are further broken down by microorganisms such as bacteria, fungi and / or enzymes that are present in a composting mixture or in the soil. Complete degradation can thus be achieved under suitable conditions.
• a thermoplastic polymer in particular a polymer of ⁇ -olefins, preferably polyethylene or ethylene copolymers, which are too small either under the action of heat and from ultraviolet light and / or from sunlight and / or under composting conditions Sharing disintegrates. Since this plastic composition also contains a natural, biodegradable substance, the resulting small plastic parts are further broken down by microorganisms such
• the aim of the present invention is to realize a plastic composition for films, foils or other molded parts, which have the desired properties of previously known thermoplastic materials, such as simple processing, high strength, water resistance, good resistance to solvents and other chemicals which meet the requirements during storage and use, but which can be rapidly degraded after use under the conditions mentioned above.
• the decomposition time of the compositions according to the invention is reduced by at least half, often by 2/3 or even more, compared to previously known products of a similar type.
• British Patent No. 1,485,833 shows that plastics with carbon-carbon bonds are biodegradable by adding a) starch granules or chemically modified starch granules and b) an oxidizable substance, such as a fatty acid and / or a fatty acid ester can be made.
• This publication also mentions that the oxidizable substance is oxidized to peroxide or hydroperoxide in contact with a transition metal salt contained in the earth, whereupon polymer chain cleavage occurs. It has been shown, however, that with a polyethylene film of this composition, most of the starch granules are covered with a polyethylene layer and therefore cannot be attacked by the microorganisms.
• thermoplastic polymers of ⁇ -olefins in particular polyethylene and polystyrene
• compounds of a transition metal in particular iron compounds
• these metal compounds are inert with the exclusion of light at normal external temperatures (below 35 ° C.).
• c) contains an optionally complex iron compound, degrades under the influence of heat (> 50 ° C) and ultraviolet light and / or solar radiation and / or composting conditions;
• Biodegradable substances such as natural starch, etherified or esterified starch or in another way, for example starch modified with silanes, are suitable as component a), the content generally mean 2 to 40% by weight, preferably 10 to 16% by weight of the composition.
• Other carbohydrates can also be used for the desired purpose. It has proven to be advantageous to use the biodegradable substance in the form of granules, which can be processed completely homogeneously into the plastic mass in a known manner.
• Component c) is an oxidizable substance which contains at least one double bond, this substance being or containing a fatty acid and / or a fatty acid ester.
• a very suitable example is natural soybean oil.
• the content of this oxidizable substance is generally up to 5% by weight, preferably 0.5 to 1.5% by weight, based on the composition.
• the iron compound which represents component b) corresponds to the general formal X-Fe, in which X represents one or more ligands, it being possible for the compound to be additionally coupled to a further ligand Y.
• Fe is used to denote iron in any known valency.
• Ligand X can be an inorganic or organic acid residue, as can a complex-bound other ligand. Examples include: OH, Cl, Br, I, oxalate, H-citrate, NO 2 , N 3 , EDTA or a carbonyl, nitrosyl or porphyrin residue.
• Suitable ligands Y are, for example, carboxylic acid ions of aromatic or aliphatic monocarboxylic acids or of dicarboxylic acids, the aliphatic carboxylic acid preferably containing 10 to 20 carbon atoms.
• the ligand Y generally serves to increase the solubility of the compound X-Fe in the polymer.
• the content of component c) is generally at least 0.01% by weight, preferably 0.15 to 0.5% by weight, based on the composition. The content can be 0.02, 0.03, 0.04% by weight, but it can also exceed 5.0% by weight.
• the optionally added catalyst is an optionally complex transition metal compound of the general formula Z'-Me a transition metal with the exception of Fe and Z 'one or more ligands.
• the following may be mentioned as examples of the ligand Z ': OH, Cl, Br, I, oxalate, H-citrate, NO 2 , N 3 , EDTA and carboxylic acid ions of aromatic or aliphatic mono- or dicarboxylic acids, wherein the aliphatic carboxylic acid preferably has 10 to 20 carbon atoms.
• the transition metals Me are primarily the transition metals of the first transition metal series of the periodic system, such as copper and vanadium.
• the content of this catalyst component is at least 0.005, preferably 0.005 to 1.0% by weight, in particular 0.01 to 0.05% by weight.
• the thermoplastic matrix consists essentially of any known thermoplastic polymer, with polymers of ⁇ -olefins, in particular polyethylene or ethylene copolymers, being preferred.
• Polyethylene here means all types of polyethylene, such as LDPE, LLDPE, LMDPE, MDPE, HDPE, ULDPE etc.
• Suitable ethylene copolymers are e.g. EVA, EBA, EAA, EMAA and ionomers.
• the present invention offers the advantage that the degradation can be controlled depending on the field of application by varying the concentration of the individual components without the plastic material suffering from a loss of its properties under the usual conditions of use.
• Particularly interesting fields of application for the compositions according to the invention are packaging materials, films for rubbish bags for compostable waste, films for agriculture, in particular those which come into contact with the earth and should disintegrate after a desired time, films for carrier bags, construction films,
• Plastic fibers and plastic tapes especially just plastic tapes, etc.
• the present invention makes it possible to manufacture environmentally friendly products without additional energy effort and can be broken down without the release of harmful substances.
• compositions according to the invention are prepared and processed into foils, films, plates or other bodies by customary methods.
• the components are advantageously added individually or in mixtures in the form of so-called masterbatches.
• plastics with CC bonds in the main chain are extremely slow biodegradable to form CO 2 and H 2 O.
• the half-life for polyethylene is extrapolated to approximately 100 years.
• radicals such as OH
• These polymer radicals are extremely reactive and can, among other things, react further with oxygen, with other polymer chains, with iron ions, with a double bond of the oxidizable substance, etc.
• Polymer chains are split, producing small chains with or without oxygen-containing groups, such as alcohols, ketones, esters, etc.
• the iron ions act both as an initiator and as a reaction promoter, while the oxidizable substance acts as a reaction promoter and in particular as a chain cleaver, since this substance tends to form peroxy or hydroxyperoxy compounds better than a saturated polymer chain, and the starch because of A large number of their hydroxyl groups appear in their composition as promoters and, in conjunction with the iron ions, as a particularly valuable co-initiator, since iron (III) hydroxide complexes are very reactive. This can be illustrated by the following equation (1):
• transition metal compounds e.g. Copper, or vanadium compounds
• Such two-stage mining is particularly recommended in the case of agricultural films that are in contact with the earth, or of scattered waste.
• the plastic parts are so small that they disintegrate even further within the earth. This would not be the case with conventional, photo-degradable plastic compositions.
• the films AI were produced by the blown film process in the usual way using masterbatches. They were all the same thickness from. Film A contained no additive to promote degradation. Films B and C, which did not contain all the necessary additives, serve as comparative experiments.
• the different levels of silicone-modified starch, iron hydroxide stearate, soybean oil and copper stearate are shown in Table 1. The change in tensile strength and elongation at break at 65 ° C and under composting conditions as a function of time was measured for each composition. With an elongation at break of less than 5% in the transverse direction the product is so brittle that measurements can no longer be carried out, so that the film can be regarded as degraded.
• Table 1 Film compositions additives in% by weight
• Plastic LDPE; MFI 1.2

Priority Applications (5)

Applications Claiming Priority (2)

Publications (1)

Family

ID=4194256

Family Applications (1)

Country Status (12)

Cited By (18)

Families Citing this family (57)

Citations (3)

Family Cites Families (5)

• 1987
  • 1987-02-27 CH CH747/87A patent/CH671961A5/de unknown
• 1988
  • 1988-02-19 EP EP88901405A patent/EP0305413B1/de not_active Expired - Lifetime
  • 1988-02-19 AT AT88901405T patent/ATE89298T1/de not_active IP Right Cessation
  • 1988-02-19 AU AU12446/88A patent/AU594864B2/en not_active Ceased
  • 1988-02-19 DE DE8888901405T patent/DE3880931D1/de not_active Expired - Fee Related
  • 1988-02-19 WO PCT/CH1988/000042 patent/WO1988006609A1/de active IP Right Grant
  • 1988-02-25 CA CA000559838A patent/CA1335613C/en not_active Expired - Fee Related
  • 1988-08-22 IL IL87513A patent/IL87513A/xx not_active IP Right Cessation
  • 1988-10-19 NO NO884660A patent/NO884660D0/no unknown
  • 1988-10-25 FI FI884918A patent/FI91772C/fi not_active IP Right Cessation
  • 1988-10-26 DK DK594988A patent/DK594988D0/da not_active Application Discontinuation
  • 1988-10-27 US US07/266,834 patent/US4931488A/en not_active Expired - Lifetime

Patent Citations (3)

Also Published As

Similar Documents

Legal Events