US2387643A - Hectograph blanket having a copy mass comprising a silicate - Google Patents
Hectograph blanket having a copy mass comprising a silicate Download PDFInfo
- Publication number
- US2387643A US2387643A US405407A US40540741A US2387643A US 2387643 A US2387643 A US 2387643A US 405407 A US405407 A US 405407A US 40540741 A US40540741 A US 40540741A US 2387643 A US2387643 A US 2387643A
- Authority
- US
- United States
- Prior art keywords
- silicate
- hectograph
- mass
- blanket
- copy
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 title description 9
- 239000000203 mixture Substances 0.000 description 14
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 10
- 108010010803 Gelatin Proteins 0.000 description 8
- 239000008273 gelatin Substances 0.000 description 8
- 229920000159 gelatin Polymers 0.000 description 8
- 235000019322 gelatine Nutrition 0.000 description 8
- 235000011852 gelatine desserts Nutrition 0.000 description 8
- 239000004615 ingredient Substances 0.000 description 7
- 235000014633 carbohydrates Nutrition 0.000 description 5
- 150000001720 carbohydrates Chemical class 0.000 description 5
- 239000003292 glue Substances 0.000 description 5
- 235000011187 glycerol Nutrition 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 229910052910 alkali metal silicate Inorganic materials 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 108090000623 proteins and genes Proteins 0.000 description 3
- 102000004169 proteins and genes Human genes 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000004115 Sodium Silicate Substances 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 239000007767 bonding agent Substances 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 229960004903 invert sugar Drugs 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 235000013379 molasses Nutrition 0.000 description 2
- 239000004014 plasticizer Substances 0.000 description 2
- 229910052911 sodium silicate Inorganic materials 0.000 description 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 2
- HNNQYHFROJDYHQ-UHFFFAOYSA-N 3-(4-ethylcyclohexyl)propanoic acid 3-(3-ethylcyclopentyl)propanoic acid Chemical compound CCC1CCC(CCC(O)=O)C1.CCC1CCC(CCC(O)=O)CC1 HNNQYHFROJDYHQ-UHFFFAOYSA-N 0.000 description 1
- CYDQOEWLBCCFJZ-UHFFFAOYSA-N 4-(4-fluorophenyl)oxane-4-carboxylic acid Chemical compound C=1C=C(F)C=CC=1C1(C(=O)O)CCOCC1 CYDQOEWLBCCFJZ-UHFFFAOYSA-N 0.000 description 1
- 229920000161 Locust bean gum Polymers 0.000 description 1
- 239000000020 Nitrocellulose Substances 0.000 description 1
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 239000004922 lacquer Substances 0.000 description 1
- 235000021388 linseed oil Nutrition 0.000 description 1
- 239000000944 linseed oil Substances 0.000 description 1
- 235000010420 locust bean gum Nutrition 0.000 description 1
- 239000000711 locust bean gum Substances 0.000 description 1
- 229920001220 nitrocellulos Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 239000001540 sodium lactate Substances 0.000 description 1
- 229940005581 sodium lactate Drugs 0.000 description 1
- 235000011088 sodium lactate Nutrition 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 235000020357 syrup Nutrition 0.000 description 1
- 239000006188 syrup Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/025—Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet
- B41M5/06—Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet using master sheets coated with jelly-like materials, e.g. gelatin
- B41M5/08—Sheet materials therefor
Definitions
- the invention relates to hectograph blankets
- Another object is to provide a hectograph blanket adapted for use in roll form.
- Another object is the provision of a blanket having a silicate tanned copy mass which is securely adhered to its backing.
- an alkali metal silicate is incorporated in a gelatinous copy mass and the mass bonded to a backing, prererably by means of an acidic type bonding agent.
- silicates occupy a peculiar position.
- a silicate may be used in relatively much larger amounts in hectograph compositions than other tanning agents.
- Their tanning properties are governed by the influence of other ingredients to a, high degree, and it is generally difilcult to cause silicate tanned masses to adhere to backing materials. 1
- silicate tanned compositions have properties more constant than those of any other type of tanned glue or gelatin in regard to the influence of water.
- silicate tanned compositions may have very nearly the same softening point at a high humidity asat a low humidity,
- hectograph compositions comprising a glue or gelatin type protein substance, about five to fifteen times the amount of this protein substance of a hydrophilic plasticizer such as glycerin, diglyceryl, glycols, carbohydrates non-crystallizing in the compositions in question, and the like.
- a hydrophilic plasticizer such as glycerin, diglyceryl, glycols, carbohydrates non-crystallizing in the compositions in question, and the like.
- glycerin or diglyceryl should be present as the major plasticizer in order to obtain the full benefits of the invention.
- a carbohydrate ingredient such as, for example, an invert sugar preparation known to the trade as Nulocrystal," corn syrup, molasses, or the like.
- This ingredient appears to be highly advantageous to the composition since without the carbohydrate present, great difliculty is encountered in obtaining adhesion between the duplication mass and the backing and also because the most desirable tanning characteristics of the silicate are not fully brought out unless a carbohydrate substance of this type is present.
- the range of the carbohydrate type ingredient may vary widely but preferably is between one per cent and thirty per cent of the total composition.
- the gelatin was allowed to swell in the water at room temperature for about one hour. It was then warmed to a temperature of 55 C. and admixed with the other ingredients which. had been pre-heated to thesame temperature.
- the sodium silicate was dissolved in an equal volume of water before being added to the mix.
- the composition thus prepared was applied in the melted state to a flexible backing material which had been provided with a coating of ten percent of naphthenic acid and two per cent of phthalic anhydride in a nitrocellulose lacquer. The hectograph rolls thus produced were allowed to age for about three weeks and were then tested and found satisfactory in every regard.
- Example 111 Parts by weight Glue (160 bloom) 50 Water '15 Glycerin 350 Molasses 25 sodium silicate 20 The soils were made according to the procedure described in Example I and were tested with the same favorable results.
- a hectograph blanket having a gelatinous copy mass comprising gelatin, glycerine, an alkali metal silicate, and, an invert sugar, the silicate being present in from one-hundredth to one-third the amount by weight of gelatin, and the glycerine being present in from five to fifteen times the weight of gelatin. WILLIAM J. CHAMPION.
Description
Patented Oct. 23,, 1945 HECTOGRAPH BLANKET HAVING A COPY MASS COMPBISIN G A SILICATE William J. Champion, Chicago, 111., assignor to Ditto, Incorporated, Chicago, 11]., a corporation of West Virginia No Drawing. Application August 4, 1941, Serial No. 405,407
1 Claim.
The invention relates to hectograph blankets,
and has for its object the provision of a hectograph blanket having a copy mass of improved mechanical resistance and low sensitivity to hydrothermal factors.
Another object is to provide a hectograph blanket adapted for use in roll form.
Another object is the provision of a blanket having a silicate tanned copy mass which is securely adhered to its backing.
Other objects and advantages will become ap parent as the following detailed description progresses.
In accordance with this invention, an alkali metal silicate is incorporated in a gelatinous copy mass and the mass bonded to a backing, prererably by means of an acidic type bonding agent.
f the various tanning agents used for imparting to duplication compositions the requisite hydrothermal resistance, silicates occupy a peculiar position. A silicate may be used in relatively much larger amounts in hectograph compositions than other tanning agents. Their tanning properties are governed by the influence of other ingredients to a, high degree, and it is generally difilcult to cause silicate tanned masses to adhere to backing materials. 1
However, silicate tanned compositions have properties more constant than those of any other type of tanned glue or gelatin in regard to the influence of water. Thus, silicate tanned compositions may have very nearly the same softening point at a high humidity asat a low humidity,
which gives them an exceptionally wide range of tolerance to conditioning.
I have further discovered that certain hectograph copy masses tanned with silicate compositions can be brought to bond readily by using acidic type bonding agents.
To carry out my invention, I prepare hectograph compositions comprising a glue or gelatin type protein substance, about five to fifteen times the amount of this protein substance of a hydrophilic plasticizer such as glycerin, diglyceryl, glycols, carbohydrates non-crystallizing in the compositions in question, and the like. However, from the practical standpoint, I found that either glycerin or diglyceryl should be present as the major plasticizer in order to obtain the full benefits of the invention. I further employ as the tanning agent an alkali silicate solution of the standard commercial type in an amount between one-hundredth and one-third oi the amount of protein present, the exact preferred amount depending upon the characteristics of the particular glue or gelatin employed and also upon the characteristics desired in the dual compositions.
I further employ a. carbohydrate ingredient such as, for example, an invert sugar preparation known to the trade as Nulocrystal," corn syrup, molasses, or the like. This ingredient appears to be highly advantageous to the composition since without the carbohydrate present, great difliculty is encountered in obtaining adhesion between the duplication mass and the backing and also because the most desirable tanning characteristics of the silicate are not fully brought out unless a carbohydrate substance of this type is present.
The range of the carbohydrate type ingredient may vary widely but preferably is between one per cent and thirty per cent of the total composition.
The invention is further illustrated by the following examples:
The gelatin was allowed to swell in the water at room temperature for about one hour. It was then warmed to a temperature of 55 C. and admixed with the other ingredients which. had been pre-heated to thesame temperature. The sodium silicate was dissolved in an equal volume of water before being added to the mix. The composition thus prepared was applied in the melted state to a flexible backing material which had been provided with a coating of ten percent of naphthenic acid and two per cent of phthalic anhydride in a nitrocellulose lacquer. The hectograph rolls thus produced were allowed to age for about three weeks and were then tested and found satisfactory in every regard.
The rolls were made according to the procedure described in Example I, and were tested with the same favorable results.
Example 111 Parts by weight Glue (160 bloom) 50 Water '15 Glycerin 350 Molasses 25 sodium silicate 20 The soils were made according to the procedure described in Example I and were tested with the same favorable results.
Sodium lactate 2 The glue, gelatin, starch and locust bean gum were allowed to swell in the water for one hour at room temperature. This mixture was then heated to 55 C. and was admixed to the other ingredients which had been pre-heated to the same temperature. The composition was then applied to a flexible backing material which had been previously coated with linseed oil which had been allowed to dry to a tenacious yet somewhat tacky set. The hectograph films thus prepared were allowed to age for. one month and were then tested and found satisfactory.
These examples have been given by way of illustration and should not be construed in any sense of limitation since it is obvious that wide variations can be made in the ingredients without departing from the spirit or scope of the invention.
I claim:
A hectograph blanket having a gelatinous copy mass comprising gelatin, glycerine, an alkali metal silicate, and, an invert sugar, the silicate being present in from one-hundredth to one-third the amount by weight of gelatin, and the glycerine being present in from five to fifteen times the weight of gelatin. WILLIAM J. CHAMPION.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US405407A US2387643A (en) | 1941-08-04 | 1941-08-04 | Hectograph blanket having a copy mass comprising a silicate |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US405407A US2387643A (en) | 1941-08-04 | 1941-08-04 | Hectograph blanket having a copy mass comprising a silicate |
Publications (1)
Publication Number | Publication Date |
---|---|
US2387643A true US2387643A (en) | 1945-10-23 |
Family
ID=23603581
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US405407A Expired - Lifetime US2387643A (en) | 1941-08-04 | 1941-08-04 | Hectograph blanket having a copy mass comprising a silicate |
Country Status (1)
Country | Link |
---|---|
US (1) | US2387643A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2767650A (en) * | 1953-07-24 | 1956-10-23 | Ellen M Yunker | Article for correcting master sheets |
US4095990A (en) * | 1976-07-26 | 1978-06-20 | Hudson Industries Corporation | Dry flexible glue compositions and method of making same |
-
1941
- 1941-08-04 US US405407A patent/US2387643A/en not_active Expired - Lifetime
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2767650A (en) * | 1953-07-24 | 1956-10-23 | Ellen M Yunker | Article for correcting master sheets |
US4095990A (en) * | 1976-07-26 | 1978-06-20 | Hudson Industries Corporation | Dry flexible glue compositions and method of making same |
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